View PDF Version
 
DOI: 10.1039/A808372J (Paper) Reference Section for: Chem. Commun., 1999, 323-324

Stereochemical control of cis- and trans-TiCl2 groups in six-coordinate complexes [(L)TiCl2] (L2– = N2O2-donor Schiff base) and reactions with trimethylaluminium to form cationic aluminium species

(Note: The full text of this document is currently only available in the PDF Version )

Jonathan P. Corden, William Errington, Peter Moore and Malcolm G. H. Wallbridge

Abstract

The first example of a cis-configuration of the TiCl2 group in a six-coordinate titanium complex [(L)TiCl2], involving a tetradentate N2O2-donor Schiff base ligand (L2–), is reported, and reactions of such complexes with trimethyl aluminium have been shown to generate cationic aluminium species.

References

  1. F. R. W. P. Wild, L. Zsolnai, G. Huttner and H.-H. Brintzinger, J. Organomet. Chem., 1982, 232, 233 CrossRef.
  2. H.-H. Brintzinger, D. Fischer, R. Mulhaupt, B. Rieger and R. M. Waymouth, Angew. Chem., Int. Ed. Engl., 1995, 34, 1143 CrossRef CAS.
  3. M. Bochmann, J. Chem. Soc., Dalton Trans., 1996, 255 RSC and references therein.
  4. H. Sinn and W. Kaminsky, Adv. Organomet. Chem., 1980, 18, 99 CAS.
  5. A. S. Guram and R. F. Jordan, Comprehensive Organometallic Chemistry, ed. M. F. Lappert, 2nd edn., Pergamon, Oxford, 1995, vol. 4, p. 589 Search PubMed.
  6. E. B. Tjaden, D. C. Swenson, R. F. Jordan and J. L. Peterson, Organometallics, 1995, 14, 371 CrossRef CAS.
  7. C. Floriani, E. Solari, F. Corazza, A. Chiesi-Villa and C. Gaustini, Angew. Chem., Int. Ed. Engl., 1989, 28, 64 CrossRef and references therein.
  8. M. Mazzanti, J.-M. Rosset, C. Floriani, A. Chiesi-Villa and C. Gaustini, J. Chem. Soc., Dalton Trans., 1989, 953 RSC.
  9. F. Corazza, E. Solari, C. Floriani, A. Chiesi-Villa and C. Gaustini, J. Chem. Soc., Dalton Trans., 1990, 1335 RSC.
  10. P. Woodman, P. B. Hitchcock and P. Scott, Chem. Commun., 1996, 2735 RSC.
  11. S. A. Fairhurst, D. L. Hughes, U. Kleinkes, G. J. Leigh, J. R. Sanders and J. Weisner, J. Chem. Soc., Dalton Trans., 1995, 321 RSC and references therein.
  12. J. P. Corden, W. Errington, P. Moore and M. G. H. Wallbridge, unpublished work.
  13. J. T. Leman, J. Braddock-Wilking, A. J. Coolong and A. R. Barron, Inorg. Chem., 1993, 32, 4324 CrossRef CAS.
  14. S. J. Dzugan and V. L. Goedken, Inorg. Chem., 1986, 25, 2858 CrossRef CAS.
  15. M. P. Coles and R. F. Jordan, J. Am. Chem. Soc., 1997, 119, 8125 CrossRef CAS.
  16. D. G. Kelly, A. J. Toner, N. M. Walker, S. J. Coles and M. B. Hursthouse, Polyhedron, 1996, 15, 4307 CrossRef CAS.
  17. G. M. Sheldrick, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
Click here to see how this site uses Cookies. View our privacy policy here.