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DOI: 10.1039/A808303G (Paper) Reference Section for: Chem. Commun., 1999, 229-230

Aufbau synthesis of a mixed-metal anion receptor cage

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Ramón Vilar, D. Michael P. Mingos, Andrew J. P. White and David J. Williams

Abstract

The isolation and structural characterisation of square planar [Ni(atu)2] (Hatu = amidinothiourea) has provided a rational basis to synthesise the novel mixed-metal cage compounds [Ni4Pd2(atu)8X]X3 (X = Cl, Br); one of these cages (when X = Cl) has been crystallographically characterised showing that the chloride anion is encapsulated in the centre of the cage forming eight hydrogen-bonds with N–H groups from the ligands and two Lewis acid–base interactions with two palladium(II) ions.

References

  1. J.-M. Lehn, Supramolecular Chemistry-Concepts and Perspectives, VCH, Weinheim, 1995 Search PubMed.
  2. M. A. Mortellaro and D. G. Nocera, J. Am. Chem. Soc., 1996, 118, 7414 CrossRef; T. W. Swager, Acc. Chem. Res., 1998, 31, 201 CrossRef CAS.
  3. P. N. W. Baxter, in Comprehensive Supramolecular Chemistry, J. P. Sauvage and M. Wais Hosseini(volume editors), Elsevier, Exeter, 1996, vol. 5, p. 165 Search PubMed.
  4. R. J. Pieters and F. Diederich, Chem. Commun., 1996, 2255 RSC; K. Konishi, S. Kimata, K. Yoshida, M. Tanaka and T. Aida, Angew. Chem., Int. Ed. Engl., 1996, 35, 2823 CAS.
  5. B. Dietrich, in Comprehensive Supramolecular Chemistry, G. W. Gokel, Elsevier, Exeter, 1996, vol. 1, p. 153 Search PubMed.
  6. P. D. Beer, Chem. Commun., 1996, 689 RSC; D. M. Rudkevich, W. Verboom, Z. Brzozka, M. J. Palys, W. P. R. V. Stauthamer, G. J. van Hummel, S. M. Franken, S. Harkema, J. F. J. Engbersen and D. N. Reinhoudt, J. Am. Chem. Soc., 1994, 116, 4341 CrossRef CAS; W. Xu, J. J. Vittal and R. J. Puddephatt, ibid., 1995, 117, 8362 Search PubMed; Supramolecular Chemistry of Anions, ed. A. Bianchi, E. García-España, K. Bowman-James, Wiley–VCH, Weinheim, 1997 Search PubMed; M. C. T. Fye, P. T. Glink, S. Menzer, J. F. Stoddart, A. J. P. White and D. J. Williams, Angew. Chem., Int. Ed. Engl., 1997, 36, 2068 Search PubMed; N. S. Fender, I. A. Kahwa, A. J. P. White and D. J. Williams, J. Chem. Soc., Dalton Trans., 1998, 1729 CrossRef CAS.
  7. M. M. G. Antonisse and D. N. Reinhoudt, Chem. Commun., 1998, 443 RSC.
  8. M. Fujita, in Comprehensive Supramolecular Chemistry, J. P. Sauvage and M. Wais Hosseini(volume editors), Elsevier, Exeter, 1996, vol. 9, p. 253 Search PubMed; C. J. Jones, Chem. Soc. Rev., 1998, 27, 289 Search PubMed; M. Fujita and K. Ogura, Bull. Chem. Soc. Jpn., 1996, 69, 1471 RSC; B. Olenyuk, A. Fechtenkötter and P. J. Stang, J. Chem. Soc., Dalton Trans., 1998, 1707 CAS.
  9. R. Vilar, D. M. P. Mingos, A. J. P. White and D. J. Williams, Angew. Chem., Int. Ed. Engl., 1998, 37, 1258 CrossRef CAS.
  10. L. Coghi, M. Lanfranchi, G. Pelizzi and P. Tarasconi, Tranistion Met. Chem., 1978, 3, 69 Search PubMed; T. Tada, Y. Kushi and Y. Yoneda, Bull. Chem. Soc. Jpn., 1982, 55, 1063 CAS; P. Lemoine, M. Chiadmi, V. Bissery, A. Tomas and B. Viossat, Acta Crystallogr., Sect. C, 1996, 52, 1430 CrossRef; R. O. C. Hart, S. G. Bott, J. L. Atwood and S. R. Cooper, J. Chem. Soc., Chem. Commun., 1992, 894 RSC.
  11. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, John Wiley and Sons, New York, 5th edn., 1988, pp. 748–752 Search PubMed.
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