The synthesis and ring-opening metathesis polymerization of peptide functionalized norbornenes

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Stefano C. G. Biagini, R. Gareth Davies, Michael North, Vernon C. Gibson, Matthew R. Giles, Edward L. Marshall and David A. Robson


Abstract

Norbornene monomers bearing two and three amino acid residues have been synthesized and the ring-opening metathesis polymerization of the monomers investigated using Mo([double bond, length half m-dash]CHCMe2Ph)([double bond, length half m-dash]N-2,6-Pri2C6H3)(OR)2, [R = CMe3 1a, CMe2CF3 1b, CMe(CF3)2 1c].


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