One-pot incorporation of titanium catalytic sites into mesoporous true liquid crystal templated (TLCT) silica

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Maria E. Raimondi, John M. Seddon, Leonardo Marchese, Enrica Gianotti, Salvatore Coluccia and Thomas Maschmeyer


Abstract

A one-pot synthesis procedure is described for the production of catalytically active titanium-incorporated mesoporous silica; the nature and accessibility of Ti(IV) sites derived from two different Ti sources was elucidated by means of catalytic tests, UV–VIS and photoluminescence spectroscopy.


References

  1. B. Notari, Adv. Catal., 1996, 41, 252.
  2. M. Taramasso, G. Perego and B. Notari, US Pat. 4410501, 1983 Search PubMed.
  3. A. Corma, M. T. Navarro and J. P. Pariente, J. Chem. Soc., Chem. Commun., 1994, 147 RSC.
  4. P. T. Tanev, M. Chibwe and T. J. Pinnavaia, Nature, 1994, 368, 321 CrossRef CAS.
  5. T. Maschmeyer, Curr. Opin. Solid State Mater. Sci., 1998, 3, 71 CrossRef CAS.
  6. T. Maschmeyer, F. Rey, G. Sankar and J. M. Thomas, Nature, 1995, 378, 159 CrossRef CAS.
  7. G. S. Attard, J. C. Glyde and C. G. Göltner, Nature, 1995, 378, 366 CrossRef CAS.
  8. M. Crocker, R. H. M. Herold and A. G. Orpen, Chem. Commun., 1997, 2411 RSC.
  9. J. V. Walker, M. Morey, H. Carlsson, A. Davidson, G. D. Stucky and A. Butler, J. Am. Chem. Soc., 1997, 119, 6921 CrossRef CAS.
  10. L. Marchese, E. Gianotti, T. Maschmeyer, G. Martra, S. Coluccia and J. M. Thomas, Nuovo Cimento Soc. Ital. Fis. D–Condens. Matter At. Mol. Chem. Phys. Fluids Plasmas Biophys., 1997, 19, 1707 Search PubMed.
  11. L. Marchese, T. Maschmeyer, E. Gianotti, S. Coluccia and J. M. Thomas, J. Phys. Chem. B, 1997, 101, 8836 CrossRef CAS.
  12. R. J. Davis and Z. F. Liu, Chem. Mater., 1997, 9, 2311 CrossRef CAS.
  13. S. Bordiga, S. Coluccia, C. Lamberti, L. Marchese, A. Zecchina, F. Boscherini, F. Buffa, F. Genoni, G. Leofanti, G. Petrini and G. Vlaic, J. Phys. Chem., 1994, 98, 4125 CrossRef CAS.
  14. J. Klaas, G. SchulzEkloff and N. I. Jaeger, J. Phys. Chem. B, 1997, 101, 1305 CrossRef CAS.
  15. S. Klein, B. M. Weckhuysen, J. A. Martens, W. F. Maier and P. A. Jacobs, J. Catal., 1996, 163, 489 CrossRef CAS.
  16. L. Lenoc, D. Trong On, S. Solomykina, B. Echchahed, F. Beland, C. Cartier dit Moulin and L. Bonneviot, Stud. Surf. Sci. Catal., 1996, 101, 611 CAS.
  17. M. E. Raimondi, E. Gianotti, L. Marchese, G. Martra, T. Maschmeyer, J. M. Seddon and S. Coluccia, in preparation.
  18. H. Yamashita, Y. Ichihashi, M. Anpo, M. Hashimoto, C. Louis and M. Che, J. Phys. Chem., 1996, 100, 16041 CrossRef CAS.
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