DOI: 10.1039/A806105J
(Paper)
Reference Section for: Chem. Commun., 1999, 55-56
Aggregation/deaggregation processes in vanadium(II) carboxylate chemistry
(Note: The full text of this document is currently only available in the PDF Version )
Peter J. Bonitatebus Jr. and William H. Armstrong
Abstract
Reactions of potassium tris(3,5-dimethylpyrazolyl)borate (KTpbMe2) with the low-valent mixed-metal complex [(thf)3V(µ-Cl)(µ-tfa)2V(thf)3][ZnCl3(thf)] resulted first in ZnCl+ abstraction and tetramer formation, then in asymmetric binuclear product formation through ligand substitution.
References
- L. Gelmini and W. H. Armstrong, J. Chem. Soc., Chem. Commun., 1989, 1904 RSC.
- P. J. Bonitatebus, Jr., S. K. Mandal and W. H. Armstrong, Chem. Commun., 1998, 939 RSC.
- W. C. A. Wilisch, M. J. Scott and W. H. Armstrong, Inorg. Chem., 1988, 27, 4333 CrossRef CAS.
- M. J. Scott, W. C. A. Wilisch and W. H. Armstrong, J. Am. Chem. Soc., 1990, 112, 2429 CrossRef CAS.
- B. Folkesson and R. Larsson, Acta Chem. Scand., Ser. A, 1979, 33, 347.
- F. A. Cotton, M. W. Extine, L. R. Falvello, D. B. Lewis, G. E. Lewis and C. A. Murillo, Inorg. Chem., 1986, 25, 3505 CrossRef CAS.
- F. A. Cotton, G. E. Lewis and G. N. Mott, Inorg. Chem., 1982, 21, 3127 and 3316 CrossRef CAS.
- P. B. Hitchcock, D. L. Hughes, L. F. Larkworthy, G. J. Leigh, C. J. Marmion and J. R. Sanders, J. Chem. Soc., Dalton Trans., 1997, 1127 RSC.
- N. P. Luneva, S. A. Mironova, A. E. Shilov, M. Y. Antipin and Y. T. Struchkov, Angew. Chem., 1993, 105, 1240 CAS.
- J. J. H. Edema, S. Hao, S. Gambarotta and C. Bensimon, Inorg. Chem., 1991, 30, 2584 CrossRef CAS.
- J. A. Davis, P. J. Bonitatebus, Jr., C. P. Davie and W. H. Armstrong, manuscript in preparation.