Isodispersion curves in flow injection analysis

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Danut-Ionel Vaireanu, Peter R. Fielden and Richard D. Snook


Abstract

This paper describes experimental equations that relate the dispersion coefficient to the geometry and hydrodynamic parameters of a flow injection system. Data are presented as isodispersion curves (similar to isothermal, isobar or isochore representations). The results present a correlated overview, which makes theoretical evaluation of the dispersion coefficient simple. Geometric and operational parameters for a flow injection system can be established when the dispersion is to be maintained within certain limits. The parameters addressed in this study are: tube length (100–1200 mm); tube diameter (0.3–0.8 mm); injected volume (93 µl); and volumetric flow rate (0.75–2.0 ml min–1).


References

  1. J. Ruzicka and E. H. Hansen, in Flow Injection Analysis, John Wiley and Sons, New York, 2nd edn., 1988, pp. 15–74 Search PubMed.
  2. M. Valcarcel and M. D. Luque de Castro, in Flow Injection Analysis: Principles and Applications, Ellis Horwood, Chichester, UK, 1987, pp. 40–84 Search PubMed.
  3. D. I. Vaireanu, P. R. Fielden and R. D. Snook, Talanta, submitted Search PubMed.
  4. D. I. Vaireanu, PhD Thesis, UMIST, Manchester, UK, 1995, pp. 125–207.
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