Luminol immobilized anion-exchange resin as an indicator phase for a chemiluminescence oxygen gas sensor

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Takuya Okamoto, Ken-ichiro Tanaka, Hajime Goto, Jin-Ming Lin, Masaaki Yamada and Yasukazu Asano


Abstract

An indicator phase, luminol immobilized on a strongly basic anion-exchange resin, was evaluated for the chemiluminescence sensing of O2 in N2 gas. The base catalyzed luminol chemiluminescence was monitored with a silicon photodiode installed in a flow cell, into which the luminol-loaded resin was packed. The signal was dependent significantly on resins and solvents used for the immobilization. Oxygen gas concentrations at ppm levels in a N2 gas and a city gas were determined by means of 1 ml sample injection.


References

  1. K. Cammann, U. Lemke, A. Rohen, J. Sander, H. Wilken and B. Winter, Angew. Chem., Int. Ed. Engl., 1991, 30, 516 CrossRef.
  2. M. Valcarcel and M. D. Luque de Castro, Flow-through (Bio)-Chemical Sensors, Elsevier, Amsterdam, 1994 Search PubMed.
  3. O. S. Wolfbeis, Fiber Optic Chemical Sensors and Biosensors, CRC Press, Boca Raton, FL, vol. I and II, 1991 Search PubMed.
  4. O. S. Wolfbeis, Anal. Proc., 1991, 28, 357 RSC.
  5. M. J. P. Leiner, Anal. Chim. Acta, 1991, 255, 209 CrossRef CAS.
  6. O. S. Wolfbeis, Fiber Optic Chemical Sensors and Biosensors, CRC Press, Boca Raton, FL, 1991, vol. I, p. 37 Search PubMed.
  7. M. Ishii and M. Yamada, J. Flow Injection Anal., 1994, 11, 154 Search PubMed.
  8. L. J. Blum, Bio- and Chemi-Luminescent Sensors, World Scientific, Singapore, 1997 Search PubMed.
  9. G. E. Collins and S. L. Rose-Pehrsson, Anal. Chem., 1995, 67, 2224 CrossRef CAS.
  10. A. Kuniyoshi, K. Hatta, T. Suzuki, A. Masuda and M. Yamada, Anal. Lett., 1996, 29, 673 CAS.
  11. W. Qin, Z. Zhang and C. Zhang, Anal. Chim. Acta, 1998, 361, 201 CrossRef CAS.
  12. T. Nakagama, M. Yamada and T. Hobo, Anal. Chim. Acta, 1990, 231, 7 CrossRef.
  13. F. Yoshimura, T. Suzuki, M. Yamada and T. Hobo, Bunseki Kagaku, 1992, 41, 191 CAS.
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