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DOI: 10.1039/A707813G (Paper) Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1998, 561-564

Conformational analysis of a fluorescent rotor, 6-(2,2-dicyanovinyl)-1-(2-hydroxyethyl)-1,2,3,4-tetrahydroquinoline

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Yukio Yamamoto, Toshiya Okajima, Yoshimasa Fukazawa, Tomomi Fujii, Yasuo Hata and Seiji Sawada

Abstract

Two stable conformations of a fluorescent rotor have been estimated by a variable temperature 1H NMR study, including NOE measurement. The height of energy barrier between them is also assessed and confirmed by MO calculation and X-ray crystal structure.

References

  1. R. O. Loutfy, Macromolecules, 1981, 14, 270 CrossRef CAS.
  2. A. Safarzadeh-Amiri, Can. J. Chem., 1984, 62, 1895 CAS.
  3. S. Lukac, J. Am. Chem. Soc., 1984, 106, 4386 CrossRef.
  4. K. Y. Law, Chem. Phys. Lett., 1980, 75, 545 CrossRef CAS.
  5. C. E. Kung and J. K. Reed, Biochemistry, 1989, 28, 6678 CrossRef CAS.
  6. S. Sawada, T. Iio, Y. Hayashi and S. Takahashi, Anal. Biochem., 1992, 204, 110 CAS.
  7. T. Iio, M. Itakura, S. Takahashi and S. Sawada, J. Biochem., 1991, 109, 499 CAS.
  8. R. O. Loutfy and B. A. Arnold, J. Phys. Chem., 1982, 86, 4205 CrossRef CAS.
  9. A. Safarzadeh-Amiri, Chem. Phys. Lett., 1986, 129, 225 CrossRef CAS.
  10. K. Yoshikawa, N. Kumazawa, H. Terada and K. Akagi, Int. J. Quantum Chem., 1980, 18, 539 CAS; K. Yoshikawa, N. Kumazawa, H. Terada and M. Ju-ichi, Bull. Chem. Soc. Jpn., 1981, 54, 1108 CAS; K. Yoshikawa and H. Terada, J. Am. Chem. Soc., 1982, 104, 7644 CrossRef CAS.
  11. M. Itoh, Y. Tanimoto and Y. Iitaka, J. Phys. Chem., 1978, 69, 816 CrossRef CAS.
  12. J. E. Kuder, W. W. Limburg, J. M. Pochan and D. Wychick, J. Chem. Soc., Perkin Trans. 2, 1977, 1643 RSC.
  13. L. A. Chetkina, E. G. Popova, B. V. Kotov, S. L. Ginzburg and E. M. Smelyanskaya, Zh. Strukt. Khim., 1976, 17, 1060 Search PubMed.
  14. E. G. Popova, L. A. Chetkina and B. V. Kotov, Zh. Strukt. Khim., 1978, 19, 1071 Search PubMed.
  15. L. C. Groenen, W. Verboom, W. H. N. Nijhuis, D. N. Reinhoudt, G. J. van Hummel and D. Feil, Tetrahedron, 1988, 44, 4637 CrossRef CAS.
  16. GAUSSIAN92, Revision C, M. J. Frisch, G. W. Trucks, M. Head-Gordon, P. M. W. Gill, M. W. Wong, J. B. Foresman, B. G. Johnson, H. B. Schlegel, M. A. Robb, E. S. Replogle, R. Gomperts, J. L. Andres, K. Raghavachari, J. S. Binkley, C. Gonzalez, R. L. Martin, D. J. Fox, D. J. Defrees, J. Baker, J. J. P. Stewart and J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1992.
  17. G. M. Sheldrick, SHELXS86, in Crystallographic Computing 3, ed. G. M. Sheldrick, C. Kruger and R. Goddard, Oxford University Press, 1985, pp. 175–189 Search PubMed.
  18. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. Garcia-Granda, R. O. Gould, J. M. M. Smits and C. Smykalla, DIRDIF92, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1992 Search PubMed.
  19. teXsan: Crystal Structure Analysis Package, Molecular Structure Corporation, 1985 and 1992.
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