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DOI: 10.1039/A706865D (Paper) Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1998, 671-678

Synthesis and configurational analysis of phosphonate cavitands

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Paola Jacopozzi, Enrico Dalcanale, Silvia Spera, Lysander A. J. Chrisstoffels, David N. Reinhoudt, Tino Lippmann and Gerhard Mann

Abstract

Synthesis, separation and configurational analysis of phosphonated and partially phosphonated cavitands derived from resorcinarenes are described. The configuration of all diastereomers has been elucidated by their 1H, 31P NMR spectra and 13C relaxation times. In all cases the course of the bridging reaction favours the formation of the sterically more crowded stereoisomers having the P[double bond, length half m-dash]O groups oriented outward with respect to the cavity.

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