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DOI: 10.1039/A805464I (Paper) Reference Section for: J. Chem. Soc., Perkin Trans. 1, 1998, 3561-3564

Montmorillonite clay catalysis. Part 14.1 A facile synthesis of 2-substituted and 2,2-disubstituted 1,3-benzodioxoles

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Tong-Shuang Li, Li-Jun Li, Bo Lu and Feng Yang

Abstract

A series of 2-substituted and 2,2-disubstituted 1,3-benzodioxoles have been synthesised by reaction of catechol and pyrogallol with corresponding aldehydes and ketones catalysed by montmorillonite KSF or K-10. The reactions are completed within 2.7–24 h to give satisfactory yields. Ketones give better yields than aldehydes, although highly sterically hindered ketones and diaryl ketones fail to react at all.

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