DOI: 10.1039/A805276J
(Paper)
Reference Section for: J. Chem. Soc., Perkin Trans. 1, 1998, 3831-3836
General and facile method for determination of configuration of steroid-17-yl methyl glycolates at C-20 based on kinetic examination
(Note: The full text of this document is currently only available in the PDF Version )
Toshio Suzuki and Hitoshi Tada
Abstract
Plots of the amount of the isomeric steroid-17-yl methyl glycolate produced by a reaction of the corresponding steroids, prednisolone, dexamethasone and hydrocortisone with cupric acetate in absolute methanol, and kinetic examination of methoxycarbonylation of their products provide a general and facile method for determination of the configuration of the steroid-17-yl methyl glycolates at C-20.
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