Issue 7, 1998

Rhodium complex-catalysed allylic alkylation of allylic acetates

Abstract

[Rh(COD)Cl]2–P(OPh)3 (P:Rh=2–3) is found to be an efficient catalyst for allylic alkylation of allylic acetates with a stabilized carbon nucleophile; alkylation at the more substituted allylic terminus is predominant.

Article information

Article type
Paper

New J. Chem., 1998,22, 659-660

Rhodium complex-catalysed allylic alkylation of allylic acetates

R. Takeuchi and N. Kitamura, New J. Chem., 1998, 22, 659 DOI: 10.1039/A802876A

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