General synthetic methodologies for the design of dinucleating ligands for copper based upon divergent 6,6′-disubstituted-3,3′-bipyridine motifs are described. Preliminary studies of model tridentate NXN (X=S, O or N) metal-binding domains for incorporation into the 3,3′-bipyridines are also described.
E. C. Constable, D. Morris and S. Carr, New J. Chem., 1998, 22, 287 DOI: 10.1039/A708334C
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