Electrooxidative rearrangement of 5,(n + 6)-dimethoxy-1-oxabicyclo[n.4.0]alkanes(n = 4,10) into ω-(2-methoxytetrahydrofur-2-yl)alkanoic esters

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Yurii N. Ogibin , Alexandre O. Terent'ev , Alexey I. Ilovaisky and Gennadii I. Nikishin


Abstract

5,(n + 6)-Dimethoxy-1-oxabicyclo[n .4.0]alkanes undergo a previously unknown oxidative rearrangement into ω-(2-methoxytetra-hydrofur-2-yl)alkanoic esters during electrolysis in methanol.


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