DOI: 10.1070/MC1998v008n04ABEH000980
(Paper)
Mendeleev Commun., 1998, 8, 140-141
Synthesis of some novel water-soluble chiral phosphines
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Andrei A. Karasik , Igor O. Georgiev , Roman I. Vasiliev and Oleg G. Sinyashin
Abstract
Two individual (RR)- and (SS)-isomers of dipotassium 1,3-di[phenyl(carboxylato)methyl]-5-phenyl-1,3,5-diazaphosphorinane have been synthesized in the reaction of bis(hydroxymethyl)phenylphosphine, paraformaldehyde and the potassium salt of (R)- or (S)-α-phenylglycine.