DOI: 10.1070/MC1998v008n04ABEH000974
(Paper)
Mendeleev Commun., 1998, 8, 143-145
Formation of stable δ-aryliron(III) complexes from the reaction of chloroiron(III) octaphenyltetraazaporphyrinate with aryl Grignard reagents
(Note: The full text of this document is currently only available in the PDF Version )
Pavel A. Stuzhin , Ol'ga V. Mal'chugina , Stanislaw Wolowiec , Lechoslaw Latos-Grazynski and Boris D. Berezin
Abstract
Chloro(octaphenyltetraazaporphyrinato)iron(III) [(Cl)FeIIIOPTAP] reacts with aryl Grignard reagents (ArMgBr; Ar = phenyl or p-tolyl) forming stable low-spin δ-aryliron(III) complexes [(Ar)FeIIIOPTAP].