DOI: 10.1070/MC1998v008n06ABEH000962
(Paper)
Mendeleev Commun., 1998, 8, 208-210
The first example of the catalytic activity of (µ-H)Os3(µ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group
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Victoriya A. Ershova , Sergei V. Tkachev , Anatoly V. Golovin and Leonid Y. Al't
Abstract
As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (µ-H)Os3(µ-OCNR1R2)(CO)10 (R1 = H, Alk; R2 = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.