DOI: 10.1070/MC1998v008n03ABEH000940
(Paper)
Mendeleev Commun., 1998, 8, 110-112
Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod
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Valeri P. Kazakov , Aleksandr I. Voloshin and Nail M. Shavaleev
Abstract
Chemiluminescence of Pr3+ is observed upon decomposition of adamantylideneadamantane-1,2-dioxetane (AAD) catalysed by β-diketonates Pr(L)3 (L = fod or dpm), the excitation of Pr3+ occurring through intracomplex energy transfer from the excited adamantanone formed upon decomposition of AAD in the complex Pr(L)3·AAD.