Cycloaddition of phosphorylnitrile oxide to C60
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Oleg G. Sinyashin , Irina P. Romanova , Farida R. Sagitova , Valeriy A. Pavlov , Valery I. Kovalenko , Yuri V. Badeev , Nail M. Azancheev , Akhat V. Il'yasov , Alla V. Chernova and Irina I. Vandyukova
Abstract
The reaction of (diisopropoxyphosphoryl)nitrile oxide with C60 leads to mono- and diadducts, which are characterized by 1H, 13C, 31P NMR, IR and UV-VIS spectroscopy as isoxazoline derivatives of fullerene; the addition takes place across a 6,6 ring junction.