Hybrid open frameworks (MIL-n). Part 4 Synthesis and crystal structure of MIL-8, a series of lanthanide glutarates with an open framework, [Ln(H2O)]2[O2C(CH2)3CO2]3·4H2O

(Note: The full text of this document is currently only available in the PDF Version )

F. Serpaggi and G. Férey


Abstract

The first series of rare-earth carboxylates with an open framework has been prepared hydrothermally (180°C, 3 days) by the action of glutaric acid on the metal chlorides in the presence of base. The crystal structure of the neodymium compound [NdIII(H2O)]2[O2C(CH2)3CO2]3·4H2O has been determined by single-crystal X-ray diffraction. The composite material crystallizes in the monoclinic space group C2/c (no. 15) with a=8.1174(1) Å, b=15.1841(3) Å, c=19.8803(3) Å, β=93.762(1)° (final agreement factors R1=0.0279, wR2=0.0693). The organic-inorganic network is three-dimensional and consists of chains of edge-sharing rare-earth polyedra NdO8(H2O) along the [100] direction, linked together by the carbon chains along two directions. The connection involves the formation of channels parallel to the rare-earth chains in which weakly bonded water molecules are incorporated. The analogous compounds were obtained with Pr, Sm, Eu, Gd, Dy, Ho and Y.


References

  1. G. Férey, J. Fluorine Chem., 1995, 72, 187 CrossRef CAS and references therein C. R. Acad. Sci. Sér. C, 1998, 2, 1 and references therein Search PubMed.
  2. M. Haouas, C. In-Gérardin, F. Taulelle, C. Estournes, T. Loiseau and G. Férey, J. Phys. Chem., 1998, 95, 320 Search PubMed.
  3. D. Riou and G. Férey, J. Solid State Chem., 1994, 111, 422 CrossRef CAS; D. Riou, F. Taulelle and G. Férey, Inorg. Chem., 1996, 35, 6392 CrossRef CAS; M. Cavellec, D. Riou, C. Ninclaus, J.-M. Grenèche and G. Férey, Zeolites, 1996, 17, 250 CrossRef CAS; M. Cavellec, D. Riou, J.-M. Grenèche and G. Férey, J. Magn. Magn. Mater., 1996, 163, 173 CrossRef CAS; M. Cavellec, J.-M. Grenèche, D. Riou and G. Férey, Microporous Mater., 1997, 8, 103 CrossRef CAS; M. Cavellec, J.-M. Grenèche and G. Férey, Microporous Mater., 1998, 20, 45 Search PubMed; M. Cavellec, C. Egger, J. Linares, M. Nogues, F. Varret and G. Férey, J. Solid State Chem., 1997, 134, 349 CrossRef CAS.
  4. A. Clearfield, Curr. Opin. Solid State Mater. Sci., 1996, 1, 268 CrossRef CAS and references therein.
  5. M. E. Thompson, Chem. Mater., 1994, 6, 1168 CrossRef CAS and references therein.
  6. G. Alberti, U. Costantino, F. Marmottini, R. Vivani and P. Zappelli, Angew. Chem., Int. Ed. Engl., 1993, 32, 1357 CrossRef; G. Alberti, F. Marmottini, S. Murcia-Mascarós and R. Vivani, Angew. Chem., Int. Ed. Engl., 1994, 33, 1594 CrossRef; L. A. Vermeulen and M. E. Thompson, Chem. Mater., 1994, 6, 77 CrossRef CAS; V. Soghomonian, Q. Chen, R. C. Haushalter and J. Zubieta, Angew. Chem., Int. Ed. Engl., 1995, 34, 223 CrossRef CAS; V. Soghomonian, R. Diaz, R. C. Haushalter, C. J. O'Connor and J. Zubieta, Inorg. Chem., 1995, 34, 4460 CrossRef CAS; H. Byrd, A. Clearfield, D. Poojary, K. P. Reis and M. E. Thompson, Chem. Mater., 1996, 8, 2239 CrossRef CAS; D. M. Poojary, B. Zhang, P. Bellinghausen and A. Clearfield, Inorg. Chem., 1996, 35, 4942; 5254 CrossRef CAS; G. Bonavia, R. C. Haushalter, C. J. O'Connor and J. Zubieta, Inorg. Chem., 1996, 35, 5603 CrossRef CAS; P. J. Zapf, D. J. Rose, R. C. Haushalter and J. Zubieta, J. Solid State Chem., 1996, 125, 182 CrossRef CAS; D. L. Lohse and S. C. Sevov, Angew. Chem., Int. Ed. Engl., 1997, 36, 1619 CrossRef CAS.
  7. S. Drumel, P. Janvier, P. Barboux, M. Bujoli-Doeuff and B. Bujoli, Inorg. Chem., 1995, 34, 148 CrossRef CAS; S. Drumel, P. Janvier, D. Deniaud and B. Bujoli, J. Chem. Soc., Chem. Commun., 1995, 1051 RSC.
  8. J. W. Bats, R. Kalus and H. Fuess, Acta Crystallogr., Sect. B, 1979, 35, 1225 CrossRef; M. C. Favas, D. L. Kepert, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1980, 54 Search PubMed; M. S. Khiyalov, I. R. Amiraslanov, F. N. Musaev and Kh. S. Mamedov, Koord. Khim., 1982, 8, 548 Search PubMed; H. Gries and H. Miklautz, Physiol. Chem. Phys. Med. NMR, 1984, 16, 105 Search PubMed; M. S. Konings, W. C. Dow, D. B. Love, K. N. Raymond, S. C. Quay and S. M. Rocklage, Inorg. Chem., 1990, 29, 1448; M. A. J. Moss and C. J. Jones, J. Chem. Soc., Dalton Trans., 1990, 581 RSC; D. Zhi-Bang, J. Zhing-Sheng, W. Ge-Cheng and N. Jia-Zan, J. Struct. Chem., 1990, 9, 64; L. Ehnebom and B. F. Pedersen, Acta Chem. Scand., 1992, 46, 126; J. Franklin and K. N. Raymond, Inorg. Chem., 1994, 33, 5794 CrossRef CAS; C. Daiguebonne, Y. Gerault, O. Guillou, A. Lecerf, K. Boubekeur, P. Batail, M. Khan and O. Khan, International Conference on f Elements 3, Paris, France, 1997 Search PubMed.
  9. S. Romero, A. Mosset and J. C. Trombe, Eur. J. Solid State Inorg. Chem., 1997, 34, 209 CAS and references therein.
  10. Handbook of Chemistry and Physics, Boca Raton, FL, 77th edn., 1996 Search PubMed.
  11. G. M. Sheldrick, SADABS, a program for the Siemens Area Detector ABSorption correction, 1994.
  12. R. Blessing, Acta Crystallogr., Sect. A, 1995, 51, 33 CrossRef.
  13. G. M. Sheldrick, SHELXTL version 5.03, software package for the Crystal Structure Determination, 1994.
  14. G. B. Deacon and R. J. Phillips, Coord. Chem. Rev., 1980, 33, 227 CrossRef CAS.
  15. N. E. Brese and M. O'Keeffe, Acta Crystallogr., Sect. B, 1991, 47, 192 CrossRef.
  16. F. Serpaggi, T. Luxbacher, A. K. Cheetham and G. Férey, J. Solid State Chem., submitted Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.