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DOI: 10.1039/A801654B (Paper) Reference Section for: J. Mater. Chem., 1998, 8, 2011-2018

Polymeric malondialdehyde dianils—a novel type of electrically conducting polymers

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Rudolf Gompper, Thomas J. J. Müller and Kurt Polborn

Abstract

The reaction of vinamidinium salts withpara-substituted aromatic diamines gives rise to polymeric 2-aryl malonaldehyde dianils in good yields. Polymeric cyanines can be obtained from tetramethoxypropane and a pentamethine cyanine, respectively, and para-substituted aromatic diamines. The degree of polymerisation Pn (n=10–40) was estimated by measuring the intrinsic viscosity η. The polymers show high electrical powder conductivities (σ=0.03–50 S cm–1) after doping with iodine or FeCl3 .

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