Spectroscopic properties of microporous layered tin sulfide materials

Abstract

¹¹⁹Sn solid state nuclear magnetic resonance, ¹¹⁹Sn Mössbauer, Fourier transform Raman and variable temperature single crystal UV–VIS absorption, emission and excitation spectra of some archetypal microporous layered tin sulfides, denoted (Et₄N)₂Sn₃S₇ (TEA-SnS-1), (C₆H₁₂N₂H)₂Sn₃S₇ (DABCOH-SnS-1), (NH₄)_0.5(Et₄N)₁ .₅Sn₃S₇ (ATEA-SnS-1) and (Pr₄N)₂Sn₄S₉ (TPA-SnS-3), are reported. The combined spectroscopic results provide a rather comprehensive picture of structure–property relations for this novel class of solids, which have the unusual ability of being able to behave as both molecular sieve and intercalation materials to a range of guests.

References

1. T. Jiang, R. L. Bedard, R. Broach, A. Lough and G. A. Ozin, J. Mater. Chem., 1998, 8, 721; G. A. Ozin, T. Jiang and A. Lough, A. Adv. Mater., 1998, 10, 42; T. Jiang, R. L. Bedard, A. J. Lough, G. A. Ozin, S. Petrov and D. Young, Chem. Mater., 1995, 7, 245.
2. G. A. Ozin, R. L. Bedard, C. L. Bowes, N. Coombs, Ö. Dag, T. Jiang, A. Lough, S. Petrov, I. Sokolov, A. Verma, G. Vovk and D. Young, Adv. Mater., 1997, 9, 1133; G. A. Ozin, R. L. Bedard, C. L. Bowes, N. Coombs, Ö. Dag, T. Jiang, A. Lough, S. Petrov, I. Sokolov, A. Verma, G. Vovk and D. Young, Nature, 1997, 388, 857.
3. G. A. Ozin, P. Enzel, R. L. Bedard and G. S. Henderson, Adv. Mater., 1995, 7, 64.
4. T. Jiang, G. A. Ozin, R. L. Bedard and A. Lough, J. Mater. Chem., 1998, 8, 733; T. Jiang, G. A. Ozin and D. Young, Adv. Mater., 1994, 6, 860.
5. H. Ahari, R. L. Bedard, C. L. Bowes, T. Jiang, A. J. Lough, G. A. Ozin, S. Petrov and D. Young, Adv. Mater., 1995, 7, 375.
6. T. Jiang, R. L. Bedard and G. A. Ozin, Adv. Mater., 1995, 7, 166.
7. H. Ahari, R. L. Bedard, C. L. Bowes, T. Jiang, G. A. Ozin and D. Young, US Patent, 5,594,263, 1997; G. A. Ozin, Supramol. Chem., 1995, 6, 125; T. Jiang, G. A. Ozin, A. Verma and R. Bedard, J. Mater. Chem., following paper.
8. C. L. Bowes, S. Petrov, G. Vovk, D. Young, G. A. Ozin and R. L. Bedard, J. Mater. Chem., 1998, 8, 711; G. A. Ozin and C. L. Bowes, Adv. Mater., 1996, 8, 13.
9. G. A. Ozin, Adv. Mater., 1992, 4, 612; M. A. Reed, Sci. Am., 1993, 118.
10. J. Herzfeld and A. E. Berger, J. Chem. Phys., 1980, 73, 6021.
11. C. Mundus, G. Taillades, A. Pradel and M. Ribes, Solid State Nucl. Magn. Reson., 1996, 7, 141.
12. R. Greatrex, N. N. Greenwood and M. Ribes, J. Chem. Soc., Dalton Trans., 1976, 500.
13. A. Vértes, L. Korecz and K. Burger, Mössbauer Spectroscopy, Akadémiai Kiadó, Budapest, 1979; Mössbauer Spectroscopy Applied to Inorganic Chemistry, ed. G. J. Long, Plenum Press, New York, 1984.
14. Infrared and Raman Spectra of Inorganic and Coordination Compounds, ed. K. Nakamoto, John Wiley & Sons, Inc., New York, 1986, 4th edn.
15. J. I. Bullock, N. J. Taylor and F. W. Parrett, J. Chem. Soc., Dalton Trans, 1972, 1844.
16. G. A. Marking and M. G. Kanatzidis, Chem. Mater., 1995, 7, 1915.
17. J. Liao, C. Varotsis and M. G. Kanatzidis, Inorg. Chem., 1993, 32, 2453.
18. E. Lifshitz, Z. Chen and L. Bykov, J. Phys. Chem., 1993, 97, 238 and references therein.
19. (a) C. Y. Fong and M. L. Cohen, Phys. Rev. B, 1972, 5, 3095; (b) R. B. Murray and R. H. Williams, J. Phys. C: Solid State Phys., 1973, 6, 3643; (c) J. Bordas, J. Robertson and A. Jakobsson, J. Phys. C: Solid State Phys., 1978, 11, 2607.
20. J. Robertson, J. Phys. C: Solid State Phys., 1979, 12, 4753.
21. E. A. Axtell III, J.-H. Liao, Z. Pikramenou and M. G. Kanatzidis, Chem. Eur. J., 1996, 2, 656; E. A. Axtell III, J.-H. Liao, Z. Pikramenou, Y. Park and M. G. Kanatzidis, J. Am. Chem. Soc., 1993, 115, 12191.
22. M. J. Powell and A. J. Grant, Nuovo Cimento B, 1977, 38, 486.