NaBi3V2O10: a new oxide ion conductor

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Derek C. Sinclair, Craig J. Watson, R. Alan Howie, Janet M. S. Skakle, Alison M. Coats, Caroline A. Kirk, Eric E. Lachowski and James Marr


Abstract

The new phase NaBi3V2O10 is reported; it was synthesised by oxide reaction at 600 °C and is triclinic with a=7.2026(10), b=7.0600(9), c=5.5312(6) Å, α=84.542(12), β=113.318(11) and γ=112.267(12)°; it is an oxide ion conductor with conductivity of ca. 1.5 mS cm–1 at 675 °C.


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