Conducting polymer image formation with photoinduced electron transfer reaction

(Note: The full text of this document is currently only available in the PDF Version )

Norihisa Kobayashi, Kenjiro Teshima and Ryo Hirohashi


Abstract

Conducting polymers are promising materials which show attractive electric and optical properties with potential importance in advanced technologies. Electrochromism is one of the noteworthy characteristics of conducting polymers and is effective in forming conducting polymer images and patterns on an electrode. Space selective image formation is also possible without an electrode by means of the combination of photoinduced electron transfer reaction with electrochromism. This has potential as a novel method of surface modification for any geometry in any place and for micropatterning. In this article, some recent aspects of (1) the electrochromism of conducting polymers and (2) the polymerization and electrochromism of conducting polymers induced by photoillumination leading to image formation are considered from the materials viewpoint. Further, possible future applications for these materials and systems are commented upon.


References

  1. H. Shirakawa, E. J. Louis, A. G. MacDiarmid, C. K. Chiang and A. J. Heeger, J. Chem. Soc., Chem. Commun., 1977, 578 RSC.
  2. Handbook of Conducting Polymers, ed. T. J. Skotheim, Marcel Dekker, New York, 1986 Search PubMed.
  3. (a) A. O. Patil, A. J. Heeger and W. Wudl, Chem. Rev., 1988, 88, 183 CrossRef CAS; (b) P. M. S. Monk, R. J. Mortimer and D. R. Rosseinsky, in Electrochromism: Fundamentals and Applications, VCH, Weinheim, 1995, p, 9 Search PubMed; (c) R. J. Mortimer, Chem. Soc. Rev., 1997, 26, 147 RSC.
  4. Abstracts, in International Conference on Electroluminescence of Molecular Materials and Related Phenomena held in Fukuoka, Japan, 1997 Search PubMed.
  5. A. F. Diaz, J. I. Castillo, J. A. Logan and W. Y. Lee, J. Electroanal. Chem., 1981, 129, 115 CrossRef CAS.
  6. A. Dall'Olio, Y. Dascola, V. Varacco and V. Brocchi, C. R. Acad. Sci. Ser. C, 1968, 267, 433 Search PubMed.
  7. A. F. Diaz and K. K. Kanazawa, J. Chem. Soc., Chem. Commun., 1979, 854 RSC.
  8. A. F. Diaz and B. Hall, IBM J. Res. Develop., 1983, 27, 342 Search PubMed.
  9. R. Bjorklund, S. Andersson, S. Allenmark and I. Lundström, Mol. Cryst. Liq. Cryst., 1985, 121, 263 CAS.
  10. M. Satoh, K. Kaneto and K. Yoshino, Synth. Met., 1986, 14, 289 CrossRef CAS.
  11. G. Tourillon and F. Garnier, J. Electroanal. Chem., 1982, 135, 173 CrossRef CAS.
  12. K. Kaneto, K. Yoshino and Y. Inuishi, Jpn. J. Appl. Phys., 1982, 21, L567.
  13. F. Garnier, G. Tourillon, M. Gazard and J. C. Dubois, J. Electroanal. Chem., 1983, 148, 299 CrossRef CAS.
  14. K. Kaneto, H. Agawa and K. Yoshino, J. Appl. Phys., 1987, 61, 1197 CrossRef CAS.
  15. S. D. D. V. Rughooputh, A. J. Heeger and F. Wudl, Synth. Met., 1987, 21, 41 CrossRef CAS.
  16. Y. Watanabe, J. Chem. Soc., Chem. Commun., 1989, 123 RSC.
  17. I. Imae, K. Nawa, Y. Ohsedo, N. Noma and Y. Shirota, Macromolecules, 1997, 30, 380 CrossRef CAS.
  18. D. M. Mohilner, R. N. Adams and W. J. Argersinger, J. Am. Chem. Soc., 1962, 84, 3612.
  19. T. Kobayashi, H. Yoneyama and H. Tamura, J. Electroanal. Chem., 1984, 161, 419 CrossRef CAS.
  20. T. Kobayashi, H. Yoneyama and H. Tamura, J. Electroanal. Chem., 1984, 177, 273.
  21. N. Kobayashi, K. Yamada and R. Hirohashi, Chem. Lett., 1990, 1983 CAS.
  22. M. C. Miras, C. Barberro, R. Kotz and O. Haars, J. Electrochem. Soc., 1991, 138, 335 CAS.
  23. N. Kobayashi, K. Yamada and R. Hirohashi, Electrochim. Acta, 1992, 37, 2101 CrossRef CAS.
  24. K. Teshima, K. Yamada, N. Kobayashi and R. Hirohashi, J. Electroanal. Chem., 1997, 426, 97 CrossRef CAS and references cited therein.
  25. M. C. Bernard, A. H. Le Goff, V. T. Bich and W. Zeng, Synth. Met., 1996, 81, 215 CrossRef.
  26. J. G. Guay and L. H. Dao, Polym. Commun., 1989, 30, 149 Search PubMed.
  27. A. Kitani, J. Yano and K. Sasaki, J. Electroanal. Chem., 1986, 209, 227 CrossRef CAS.
  28. P. J. S. Foot and R. Simon, J. Phys. D, Appl. Phys., 1989, 22, 1598 CrossRef CAS.
  29. H. Yashima, M. Kobayashi, K.-B. Lee, A. J. Heeger and F. Wudl, J. Electrochem. Soc., 1987, 134, 46 CAS.
  30. N. M. Hanly, D. Bloor, A. P. Monkman, R. Bonnett and J. M. Ribo, Synth. Met., 1993, 60, 195 CAS.
  31. A. Bolognesi, M. Catellani, S. Destri, R. Zamboni and C. Taliani, J. Chem. Soc., Chem. Commun., 1988, 246 RSC.
  32. J. Guay, R. Payston and L. H. Dao, Macromolecules, 1990, 23, 3598 CrossRef CAS and references cited therein.
  33. H. Hashimoto, N. Oyama, T. Ohsaka, S. Tanaka and T. Miyashi, J. Electrochem. Soc., 1991, 138, 2003 and references cited therein.
  34. J. L. Reddinger and J. R. Reynolds, Macromolecules, 1997, 30, 673 CrossRef CAS.
  35. X. Ren, S. K. Mandal and P. G. Pickup, J. Electroanal. Chem., 1995, 389, 115 CrossRef CAS.
  36. C. M. Elliott, S. J. Schmittle, J. G. Redepenning and E. M. Balk, J. Macromol. Sci.-Chem., 1988, A25, 1215 Search PubMed.
  37. M. Velazquez, T. A. Skotheim and C. A. Linkous, Synth. Met., 1986, 15, 219 CrossRef.
  38. M. Velazquez, T. A. Skotheim and C. A. Linkous, Polym. Prepr., 1984, 25, 258 Search PubMed.
  39. T. Iyoda, M. Aiba, T. Saiki, K. Honda and T. Shimizu, J. Chem. Soc., Faraday Trans., 1991, 87, 1765 RSC.
  40. T. Amemiya, K. Itoh and A. Fujishima, Ber. Bunsenges. Phys. Chem., 1989, 92, 682 Search PubMed.
  41. S. Kuwabata, K. Mitsui and H. Yoneyama, J. Electroanal. Chem., 1990, 281, 97 CrossRef CAS.
  42. H. Yoneyama and Y. Shoji, J. Electrochem. Soc., 1990, 137, 3826 CAS.
  43. H. Yoneyama, S. Hirao and S. Kuwabata, J. Electrochem. Soc., 1992, 139, 3141 CAS.
  44. A. M. Rocco, M.-A. DePao, A. Zanelli and M. Mastragostine, Electrochim. Acta, 1996, 41, 2805 CrossRef CAS.
  45. T. Ohtsuka, T. Wakabayashi and H. Einaga, Synth. Met., 1996, 79, 235 CrossRef CAS.
  46. M. Sima and T. Visan, Romanian J. Phys., 1995, 40, 1073 Search PubMed.
  47. N. Kobayashi, R. Hirohashi, H. Ohno and E. Tsuchida, Solid State Ionics, 1990, 40/41, 491 CrossRef and references cited therein.
  48. N. Leventis and Y. C. Chung, J. Electrochem. Soc., 1990, 137, 3321 CAS.
  49. R. Noufi, D. Tench and L. F. Warren, J. Electrochem. Soc., 1980, 127, 2310 CAS.
  50. T. Skotheim, I. Lundström and J. Prejza, J. Electrochem. Soc., 1981, 128, 1625 CAS.
  51. M. Okano, K. Itoh, A. Fujishima and K. Honda, Chem. Lett., 1986, 469 CAS.
  52. H. Yoneyama and M. Kitayama, Chem. Lett., 1986, 657 CAS.
  53. H. Yoneyama, K. Kawai and S. Kuwabata, J. Electrochem. Soc., 1988, 135, 1699 CAS.
  54. T. Shimizu, T. Iyoda and K. Honda, Pure Appl. Chem., 1988, 60, 1025.
  55. H. Segawa, T. Shimizu and K. Honda, J. Chem. Soc., Chem. Commun., 1989, 132 RSC.
  56. J.-M. Kern and J.-P. Sauvage, J. Chem. Soc., Chem. Commun., 1989, 654 RSC.
  57. J. F. Rabek, J. Lucki, M. Zuber, B. J. Qu and W. F. Shi, J. Macromol. Sci., Pure Appl. Chem., 1992, A29, 297 CAS.
  58. K. Teshima, K. Yamada, N. Kobayashi and R. Hirohashi, Chem. Commun., 1996, 829 RSC.
  59. K. Teshima, S. Uemura, N. Kobayashi and R. Hirohashi, in contribution. Note; Flemion is perfluorosulfonic acid polymer (ref. 72) with a similar structure to Nafion and is obtainable from Asahi Glass Co. Ltd.
  60. E. W. Meijer, S. Nijhuis and F. C. B. M. Vroonhoven, J. Am. Chem. Soc., 1988, 110, 7209 CrossRef CAS.
  61. M. Kitano, T. Iyoda and T. Shimizu, Polym. J., 1995, 27, 875 Search PubMed.
  62. M. Fujitsuka, T. Sato, H. Segawa and T. Shimizu, Chem. Lett., 1995, 99 CAS.
  63. N. Teramae, T. Uchida and T. Ishioka, Kagakukogyo, 1994, 45, 952 CAS.
  64. M. S. Paley, D. O. Frazier, H. Abdeldeyem, S. Armstrong and S. P. McManus, J. Am. Chem. Soc., 1995, 117, 4775 CrossRef CAS.
  65. O. Inganäs and I. Lundström, J. Electrochem. Soc., 1984, 131, 1129.
  66. H. Yoneyama, S. Hirao and S. Kuwabata, J. Electrochem. Soc., 1992, 139, 3141 CAS.
  67. S. Kuwabata, N. Takahashi, S. Hirao and H. Yoneyama, Chem. Mater., 1993, 5, 437 CrossRef CAS.
  68. H. Yoneyama, N. Takahashi and S. Kuwabata, J. Chem. Soc., Chem. Commun, 1992, 716 RSC.
  69. S. Kuwabata, A. Kishimoto and H. Yoneyama, J. Electroanal. Chem., 1994, 377, 261 CrossRef CAS.
  70. H. Yoneyama, M. Tokuda and S. Kuwabata, Electrochim. Acta, 1994, 39, 1315 CrossRef CAS.
  71. K. Yamada, M. Syakuto, K. Teshima, N. Kobayashi and R. Hirohashi, J. Soc. Photogr. Sci. Technol. Jpn., 1994, 57, 445 Search PubMed.
  72. N. Kobayashi, T. Yano, K. Teshima and R. Hirohashi, Electrochim. Acta, in the press Search PubMed.
  73. N. Kobayashi, Y. J. Kim, K. Teshima and R. Hirohashi, unpublished work.
  74. K. Yoshino, M. Ozaki and R. Sugimoto, Jpn. J. Appl. Phys., 1985, 24, L373.
  75. K. Yoshino, H. Takahashi and R. Sugimoto, Jpn. J. Appl. Phys., 1991, 30, L657 CAS.
  76. M. S. A. Abdou, Z. W. Xie, A. M. Leung and S. Holdcroft, Synth. Met., 1992, 52, 159 CrossRef CAS.
  77. L. Dai, H. J. Griesser, X. Hong, A. W. H. Mau, T. H. Spurling, Y. Yang and J. W. White, Macromolecules, 1996, 29, 282 CrossRef CAS.
  78. M. Angelpoulos, J. M. Shaw and K.-L. Lee, Polym. Eng. Sci., 1992, 32, 1535 Search PubMed.
  79. R. M. Leasure, W. Ou, J. A. Moss, R. W. Linton and T. J. Meyer, Chem. Mater., 1996, 8, 264 CrossRef CAS.
  80. M. Sandberg, S. Tanaka and K. Kaeriyama, Synth. Met., 1993, 60, 171 CAS.
  81. M. S. A. Abdou and S. Holdcroft, Chem. Mater., 1994, 6, 962 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.