Synthesis of layered nickel phosphonate materials based on a topotactic approach

Abstract

Layered nickel phosphonate materials Ni(O₃PR)H₂O [with R=C₆H₅ , CH₃ , (CH₂)₂CO₂H, (CH₂)₂Br and CH₂C₆H₅ ] have been prepared by heating nickel(ii) hydroxide with a stoichiometric quantity of the relevant phosphonic acid at the melting temperature of the phosphonic acid. Samples of Ni(O₃PC₆H₅)H₂O and Ni(O₃PCH₃)H₂O prepared by this method are identical to those prepared previously by other synthetic routes. In addition, the novel materials Ni[O₃P(CH₂)₂CO₂H]H₂O, Ni[O₃P(CH₂)₂Br]H₂O and Ni(O₃PCH₂C₆H₅)H₂O have been synthesised by this method. The structural properties of these materials are assessed in detail, and compared with the structural properties of other materials containing the same phosphonates but different divalent metals. The synthetic method reported here appears to be a general approach for preparation of layered metal phosphonates, for cases in which the phosphonic acid undergoes melting rather than decomposition at elevated temperatures.

References

1. M. B. Dines and P. Di Giacomo, Inorg. Chem., 1981, 20, 92.
2. G. Alberti, M. Casciola, U. Costantino and R. Vivani, Adv. Mater., 1996, 8, 291.
3. A. Clearfield and U. Costantino, in Comprehensive Supramolecular Chemistry, ed. G. Alberti and T. Bein, Pergamon Press, Oxford, 1996, vol. 7, pp. 107–149.
4. F. J. Frink, R.-C. Wang, J. L. Colón and A. Clearfield, Inorg. Chem., 1991, 30, 1438.
5. K. Martin, P. J. Squattrino and A. Clearfield, Inorg. Chim. Acta, 1989, 155, 7.
6. Y. Ortiz-Avila, P. R. Rudolf and A. Clearfield, Inorg. Chem., 1989, 28, 2137.
7. D. Cunningham and P. J. D. Hennelly, Inorg. Chim. Acta, 1979, 37, 95.
8. S. Drumel, P. Janvier, D. Deniaud and B. Bujoli, J. Chem. Soc., Chem. Commun., 1995, 1051.
9. S. Drumel, P. Janvier, P. Barboux, M. Bujolidoeuff and B. Bujoli, Inorg. Chem., 1995, 34, 148.
10. G. Cao, H. Lee, V. M. Lynch and T. E. Mallouk, Inorg. Chem., 1988, 27, 2781.
11. M. D. Poojary, H.-L. Hu, F. L. Campbel III and A. Clearfield, Acta Crystallogr., Sect. B, 1993, 49, 996.
12. S. Carlino, M. J. Hudson, S. W. Husain and J. A. Knowles, Solid State Ionics, 1996, 84, 117.
13. G. Alberti, U. Costantino, M. Casciola and R. Vivani, Solid State Ionics, 1991, 46, 61.
14. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley-Interscience, 5th edn., 1988.