DOI: 10.1039/A805806G
(Paper)
Reference Section for: J. Chem. Res. (S), 1998, 728-729
The Wittig Reaction of Fluorinated Amides: an Unusual Fragmentation of Oxaphosphetane Intermediates
(Note: The full text of this document is currently only available in the PDF Version )
Stéphane Boulard, Paul Gordon and Stephen P. Stanforth
Abstract
The fluorinated amides 1a–e reacted with phosphorane 2 in toluene at reflux yielding a tautomeric mixture of enamines 5a–e and imines 6a–evia a putative oxaphosphetane intermediate 3.
References
- B. E. Maryanoff and A. B. Reitz, Chem. Rev., 1989, 89, 863 CrossRef CAS.
- P. J. Murphy and J. Brennan, Chem. Soc. Rev., 1988, 17, 1 RSC.
- W. Flitsch and S. R. Schlinder, Synthesis, 1975, 685 CrossRef CAS.
- J.-P. Bégué and D. Mesureur, Synthesis, 1989, 309 CAS.
- J.-P. Bégué, D. Bonnet-Delphon, D. Mesureur, G. Née and S.-W. Wu, J. Org. Chem., 1992, 57, 3807 CrossRef CAS.
- E. J. Latham and S. P. Stanforth, Chem. Commun., 1996, 2253 RSC.
- E. J. Latham and S. P. Stanforth, J. Chem. Soc., Perkin Trans. 1, 1997, 2059 RSC.
- E. J. Latham, S. M. Murphy and S. P. Stanforth, Tetrahedron Lett, 1994, 35, 3395 CrossRef CAS.
- E. J. Latham, S. M. Murphy and S. P. Stanforth, Tetrahedron, 1995, 51, 10385 CrossRef CAS.