DOI: 10.1039/A805642K
(Paper)
Reference Section for: J. Chem. Res. (S), 1998, 678-678
The Regio- and Stereo-chemistries of the (2π+2π) Photocycloaddition of Electron-deficient Ethenes to Isoquinolin-1(2H)-one
(Note: The full text of this document is currently only available in the PDF Version )
Nader Al-Jalal, Christopher Covell and Andrew Gilbert
Abstract
The (2π+2π) photocycloaddition of isoquinolin-1(2H)-one to electron-deficient ethenes is efficient, regiospecific and highly stereoselective: 254nm irradiation of the acrylonitrile adduct induces retroadditon and rearrangement to an N-vinylisoindolinone with equal efficiencies.
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