Oxidative Addition of Tetraethylthiuram Disulfide to Tin(II) Catecholate: X-Ray and Theoretical Investigations

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Radhakrishnan Selvaraju, Parthasarathi Laavanya, Krishnaswamy Panchanatheswaran, Lorenzo Pellerito and G. La Manna


Abstract

The reaction of tin(II) catecholate with tetraethylthiuram disulfide yields the addition product (o-C6H4O2)Sn[S2CN(C2H5)2]2, whose structure has been elucidated by X-ray crystallography, as a rare neutral tris chelate of tin(IV).


References

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  2. J. J. P. Stewart, MOPAC6.0, QCMP 137, QCPE, Bloomington, IN, USA Search PubMed.
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