DOI: 10.1039/A802040J
(Paper)
Reference Section for: J. Chem. Res. (S), 1998, 400-401
Microwave Enhanced Hydrogenation Reactions using Solid Hydrogen, Deuterium and Tritium Donors
(Note: The full text of this document is currently only available in the PDF Version )
Mohammed H. Al-Qahtani, Nicola Cleator, Timothy N. Danks, Russell N. Garman, John R. Jones, Stefan Stefaniak, Alan D. Morgan and Alan J. Simmonds
Abstract
Microwave enhanced hydrogenation reactions in which H2/D2/T2 gases are replaced by various formates proceed very rapidly; the pattern of labelling can be easily modified and the advantages are particularly noteworthy in the case of tritium where problems associated with handling T2 gas are avoided.
References
- M. Hudlický, Reductions in Organic Chemistry, ACS Monograph 188, American Chemical Society, Washington, DC, 2nd edn., 1996 Search PubMed.
- A. F. Thomas, Deuterium Labelling in Organic Chemistry, Appleton Century Crofts, New York, 1971 Search PubMed.
- E. A. Evans, Tritium and its Compounds, Butterworths, London, 2nd edn., 1974 Search PubMed.
- J. R. Jones, (Editor), Isotopes: Essential Chemistry and Applications II, The Royal Society of Chemistry, London, 1988 Search PubMed.
- I. D. Entwistle, R. A. W. Johnstone and A. H. Wilby, Chem. Rev., 1985, 85, 129 CrossRef CAS.
- R. Gedye, F. Smith, K. Westaway, A. Humera, L. Baldisera, L. Laberge and L. Roussell, Tetrahedron Lett., 1986, 26, 279 CrossRef.
- R. J. Giguere, T. L. Bray, S. M. Duncan and G. Majetich, Tetrahedron Lett., 1986, 27, 4945 CrossRef CAS.
- D. R. Hwang, S. M. Moerlein, L. Lang and M. J. Welch, J. Chem. Soc., Chem. Commun., 1987, 1799 RSC.
- S. A. Stone-Elander, N. Elander, J. O. Thorell, G. Solas and J. Svennebrink, J. Labelled Compd. Radiopharm., 1994, 34, 949 CAS.