Predicting Protonation Constants in Polyazaalkanes

(Note: The full text of this document is currently only available in the PDF Version )

José Manuel Lloris, Ramón Martínez-Máñez, Eduardo Perales and Juan Soto


Abstract

An easy model which allows to calculate protonation constants in polyamines containing n equivalent or near equivalent protonation sites from simple molecular analysis is reported.


References

  1. (a) See for example: F. Lidon, The Chemistry of Macrocyclic Ligand Complexes, Cambridge University Press, Cambridge, UK, 1989 Search PubMed; (b) R. M. Izzat, K. Pawlak, J. S. Bradshaw and R. L. Bruening, Chem. Rev., 1991, 91, 1721 CrossRef CAS; (c) A. Bianchi, M. Micheloni and P. Paoletti, Coord. Chem. Rev., 1991, 110, 17 CrossRef CAS.
  2. See for example: (a) A. Bencini, A. Bianchi, M. I. Burguete, A. Domenech, E. Garcia-Espafia, S. V. Luis, M. A. Ninfio and J. A. Ramirez, J. Chem. Soc., Perkin Trans. 2, 1991, 1445 RSC; (b) A. Andrés, C. Bazzicalupi, A. Bencini, A. Bianchi, V. Fusi, E. García-España, C. Giorgi, N. Nardi, P. Paoletti, J. A. Ramírez and B. Vatancoli, J. Chem. Soc., Perkin Trans. 2, 1994, 2367 RSC.
  3. See for example: J. Clark and D. D. Perrin, Quart. Rev., 1964, 18, 295 Search PubMed.
  4. PCMODEL, Molecular Modelling for Personal Computers and Workstations, Serene Software, 1988 Search PubMed.
  5. J. A. Aguilar, A. Bianchi, E. Garcia-Espanfia, S. V. Luis, J. M. Llinares, J. A. Ramirez and C. Soriano, J. Chem. Soc., Dalton Trans., 1994, 637 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.