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DOI: 10.1039/A801418C (Paper) Reference Section for: J. Chem. Res. (S), 1998, 624-625

Synthesis and First Separation of Chiral Trimetal Carbonyl Clusters containing an RuCoMo(µ3-S) Core

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Er-Run Ding, Qing-Shan Li, Yuan-Qi Yin and Jie Sun

Abstract

Clusters RuCoMo(µ3-S)(CO)8C5H4R [R=HC(O) 2, MeC(O) 3, PhC(O) 4, MeOC(O)C6H4C(O) 5] were obtained by the reaction of (µ3-S)RuCo2(CO)91 and [M(CO)3RC(O)Cp]–, clusters 3 and 5 have been solved by single crystal X-ray diffraction and cluster 3 was resolved on amylopection tris(phenylcarbamate) (ATP) chiral stationary phases (CSPs).

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