Analytical Applications of Raman Spectroscopy in Organic Chemistry: Influence of the Position, Stereochemistry and Substitution Pattern of the Double Bond on the ν(C[double bond, length as m-dash]C) and ν(sp2-CH) Stretching Bands in the Raman Spectra of Alkenyl Methyl Ethers

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Richard D. Bowen, Howell G. M. Edwards, Dennis W. Farwell, Irene Rusike† and Darren M. Saunders†


Abstract

The Raman spectra of 29 alkenyl methyl ethers, CnH2n–1OMe, of diverse structure containing up to seven carbon atoms reveal reliable correlations between the wavenumber of the ν(C[double bond, length as m-dash]C) and ν(sp2-CH) stretching bands and the position, stereochemistry and substitution pattern of the double bond.


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