Double Palladium(II)-catalyzed Allylic Transpositions. Stereoselective Synthesis of Dihydroxy-(E,Z,E)-conjugated Trienes

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Catherine Martin, Michel Bortolussi and Robert Bloch


Abstract

A versatile and stereoselective synthesis of dihydroxy-(E,Z,E)-conjugated trienes, involving a palladium(II)-catalyzed two-fold [3,3] rearrangement, is reported.


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