DOI: 10.1039/A708947C
(Paper)
Reference Section for: J. Chem. Res. (S), 1998, 396-397
Preparation of α-Arylseleno-substituted Zinc and Copper Organometallics and their Application in the Synthesis of α-Arylselenomethyl Ketones
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Xian Huang and De-Hui Duan
Abstract
α-Arylseleno-substituted zinc and copper organometallics, prepared by zinc insertion into the carbon–chlorine bond of α-chloromethyl aryl selenides and with CuCN–2LiCl transmetallation to the corresponding copper reagents, react with acyl chlorides to give α-arylselenomethyl ketones based on the formation of a new carbon–carbon bond.
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