Substituent Effects on the Redox Properties of some Bis(N-Arylpyrrole-2-carboxaldiminato)-copper(II) Complexes†

(Note: The full text of this document is currently only available in the PDF Version )

Aminou Mohamadou, Jean-Pierre Barbier and Michel Aplincourt


Abstract

Cyclic voltammetry shows that the reduction of bis(N-para and meta substituted phenylpyrrole-2-carboxaldiminato)copper(II) complexes are considered quasireversible and irreversible in the case of ortho derivatives, the stereochemical effect being more important than the inductive effect.


References

  1. A. Mohamadou, J. P. Barbier and R. P. Hugel, Polyhedron, 1992, 11, 2697 CrossRef CAS.
  2. H. Yokoi and A. W. Addison, Inorg. Chem., 1977, 16, 1341 CrossRef CAS.
  3. A. W. Addision and J. H. Stenhouse, Inorg. Chem., 1978, 17, 2161 CrossRef CAS.
  4. A. Nurhadi, E. Graf and M. Gross, Electrochim. Acta, 1992, 37, 209.
  5. G. S. Patterson and R. H. Holm, Bioinorg. Chem., 1975, 4, 257 CrossRef CAS.
  6. M. A. Santos and M. L. Simoes Gonçalves, Electrochim. Acta, 1991, 36, 1997 CrossRef.
  7. R. H. Holm, A. Chakravorty and G. O. Dudeck, J. Am. Chem. Soc., 1964, 86, 379 CrossRef CAS.
  8. A. J. Bard and L. R. Faulker, Electrochemical Methods: Fundamentals and Applications, Wiley, New York, 1980, p. 249 Search PubMed.
  9. H. Matsuda and Y. Ayabe, Z. Elektrochem., 1955, 59, 494 Search PubMed.
  10. R. S. Nicholson and I. Shain, Anal. Chem., 1964, 36, 706 CrossRef CAS.
  11. J. Sima, P. Fodran, J. Hledik and D. Valigura, Inorg. Chim. Acta, 1984, 81, 143 CrossRef CAS.
  12. A. Kotocova, D. Valigura, P. Fodran and J. Sima, Inorg. Chim. Acta, 1984, 88, 135 CrossRef CAS.
  13. L. Lisowski, M. Grazeszczuk and L. Grazynski, Inorg. Chim. Acta, 1989, 161, 135 CrossRef CAS.
  14. B. R. James and R. J. P. Williams, J. Chem. Soc., 1961, 2007 RSC.
  15. D. Perrin, W. L. F. Armarego and R. D. Perrin, Purification of Laboratory Chemicals, Pergamon, Oxford, 3rd edn., 1988 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.