DOI: 10.1039/A708181B
(Paper)
Reference Section for: J. Chem. Res. (S), 1998, 126-127
The Stereochemistry of an Elimination Reaction accompanying the Hydroboration of a Steroidal Allylic Alcohol†
(Note: The full text of this document is currently only available in the PDF Version )
James R. Hanson, Mansur D. Liman and Cavit Uyanik
Abstract
Deuterium labelling studies have shown that the facile elimination of the 5β-hydroxy group observed in the course of hydroboration of a 5β-hydroxyandrost-3-ene may involve a trans diaxial borane-borinate elimination coupled with a syn transfer of hydrogen from the borinate.
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