Efficient and Highly Regioselective Formation of the C[double bond, length as m-dash]N Double Bond via Phosphoryl Thiourea Compounds†

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Jia Zhou and Ru-Yu Chen


Abstract

Desulfurization of open chain phosphoryl thiourea compounds utilizing the Ag+–ROH system under mild conditions affords, regioselectively, depending upon the substrates used, the corresponding imino-ester derivatives in good yields.


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