Redox Chemistry of [Fe2(CN)10]4–. Part 4.† Reaction with L-Cysteine‡

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Floyd A. Beckford, Deon Bennet, Tara P. Dasgupta and Geoffrey Stedman


Abstract

L-Cysteine reduces [Fe2(CN)10]4– to [Fe2(CN)10]6– in a two stage process, a rapid reduction to [Fe2(CN)10]5– followed by a slower second order reaction involving HSCH2CH(NH3+)CO2 and a conjugate base.


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