EPR of Powder Copper Phthalocyaninate Substituted with Eight Tetraazamacrocycles and its Nonanuclear Ni2+, Co2+, Zn2+ and Cu2+ Complexes

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Fevzi Koeksal, Fatih Ucun, Erbil Aǧar and Ibrahim Kartal


Abstract

Variations of the electron paramagnetic resonance parameters of the copper phthalocyaninates due to the paramagnetic and diamagnetic metal ions substituted into the outer cells of eight 12-membered tetraazamacrocycles are found to be very slight and this slight difference is attributed to the electronegativity of the substituted metal.


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