DOI: 10.1039/A802967I
(Paper)
J. Chem. Soc., Faraday Trans., 1998, 94, 2627-2632
Metal complexes in a constrained environment
197Au Mössbauer study and chemical behaviour of the Au[S![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
C(NH2)2]2+ cation exchanged in unpillared and in aluminium pillared synthetic beidellite clay
(Note: The full text of this document is currently only available in the PDF Version )
Lorenzo Stievano, Sandro Calogero, Loretta Storaro, Maurizio Lenarda and Friedrich E. Wagner
Abstract
Intercalation of the gold thiourea (T) complex, AuT2+, into beidellite clay and aluminium pillared beidellite was studied by 197Au Mössbauer spectroscopy, X-ray diffraction and infrared spectroscopy. At a concentration close to the cation exchange capacity, the AuT2+ complexes are found to be oriented diagonal to the clay sheets, while at a much lower concentration and in the pillared beidellite they lie flat in the interlayer spacing. Thermal decomposition of the intercalated AuT2+ was studied at temperatures up to 400 °C.