High resolution vibration–rotation spectra of the arsine local mode (110 A1/E) band

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Sheng-fu Yang, Hai Lin, Doug Wang and Qing-shi Zhu


Abstract

The high resolution Fourier transform spectrum of arsine was revisited in the region 4000–4350 cm-1 at a resolution of 0.006 cm-1. Altogether 189 energy levels of the local mode (110 A1/E) states were assigned by use of the ground state combination difference method. The vibration–rotation parameters were obtained from a weighted non-linear least-squares fit and discussed in the local mode model.


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