Thermal expansion behavior of a shock-synthesized B[ndash ]C[ndash ]N heterodiamond

Abstract

The thermal expansion coefficient of BC_2.5N heterodiamond determined by means of high-temperature X-ray diffraction, is negligible up to 800°C, it changes abruptly in the range 900–1100°C and increases steadily above 1100°C. The thermal expansion coefficient is ca. 5.5×10^-6 K^-1 in the range 1100–1300°C. This expansion coefficient is in fairly good agreement with that of cubic BN at high temperatures. The rapid expansion preceding the steady expansion is unknown for diamond and cubic BN. The thermal expansion behavior is discussed from a structural viewpoint.

References

1. G. A. Slack and S. F. Bartram, J. Appl. Phys., 1975, 46, 89.
2. T. Komatsu, M. Nomura, Y. Kakudate and S. Fujiwara, J. Mater. Chem., 1996, 6, 1799.
3. T. Komatsu, Y. Kakudate and S. Fujiwara, J. Chem. Soc., Faraday Trans., 1996, 92, 5067.
4. T. Sasaki and N. Bartlett, Proc. 197th ACS National Meeting(Inorganic), ACS, Washington, DC, 1990, p. 46.
5. J. B. Wachtman Jr, T. G. Scuderi and G. W. Cleek, J. Am. Ceram. Soc., 1962, 45, 319.
6. K. A. Gingerich, J. Chem. Soc., Chem. Commun., 1974, 00, 199.
7. H. J. McSkimin and P. J. Andreatch, J. Appl. Phys., 1972, 43, 2944.
8. E. Knittle, R. M. Wentzcovitch, R. Jeanloz and M. L. Cohen, Nature (London), 1989, 337, 349.