A rare uranium(III) complex of a tripodal aromatic amine and its lanthanum analogue

Abstract

The crystal structure of the first U(III) complex of the heptadentate tripodal aromatic amine tris[(2,2′-bipyridin-6-yl)methyl]amine and of its La(III) analogue have been determined.

References

1. M. Ephritikine, New J. Chem., 1992, 16, 451.
2. I. Santos, A. Pires de Matos and A. G. Maddock, Adv. Inorg. Chem., 1989, 34, 65.
3. A. J. Amoroso, J. C. Jeffery, P. L. Jones, J. C. McCleverty, L. Rees, A. L. Rheingold, Y. Sun, J. Takats, S. Trofimenko, M. D. Ward and G. P. A. Yap, J. Chem. Soc., Chem. Commun., 1995, 1881; A. Carvalho, A. Domingos, P. Gaspar, N. Marques, A. Pires de Matos and I. Santos, Polyhedron, 1992, 11, 1481; P. Roussel and P. Scott, J. Am. Chem. Soc., 1998, 120, 1070.
4. K. N. Nash, Solvent Extr. Ion Exch., 1993, 11, 729.
5. C. Musikas, Actinide-Lantanide Group Separations using Sulfur and Nitrogen Donor Extractants, in Actinide/Lanthanide Separations Proceedings of an International Symposium, Honolulu, Hawaii, 16–22 Dec. 1984, World Scientific, Singapore, 1985, p. 19.
6. F. A. Hart and M. Tajik, Inorg. Chim. Acta, 1983, 71, 169.
7. R. Wietzke, M. Mazzanti, J.-M. Latour, J. Pecaut, P.-Y. Cordier and C. Madic, Inorg. Chem., in the press.
8. R. Ziessel and J.-M. Lehn, Helv. Chim. Acta, 1990, 73, 1149.
9. V. Balzani, E. Berghmans, J.-M. Lehn, N. Sabbatini, R. Terörde and R. Ziessel, Helv. Chim. Acta, 1990, 73, 2083.
10. L. R. Avens, S. G. Bott, D. L. Clark, A. P. Sattelberger, J. G. Watkin and B. D. Zwick, Inorg. Chem., 1994, 33, 2248.
11. A. R. Schake, L. R. Avens, C. J. Burns, D. L. Clark, A. P. Sattelberger and W. H. Smith, Organometallics, 1993, 12, 1497; A. Zalkin and J. G. Brennan, Acta Crystallogr., Sect. C, 1987, 43, 1919; H. J. Wasserman, D. C. Moody, R. T. Paine, R. R. Ryan and K. V. Salazar, J. Chem. Soc., Chem. Commun., 1984, 533.
12. A. R. Al-Karaghouli and J. S. Wood, Inorg. Chem., 1972, 11, 2293.
13. M. Fréchette, I. R. Butler, R. Hynes and C. Detellier, Inorg. Chem., 1992, 31, 1650; M. Fréchette and C. Bensimon, Inorg. Chem., 1995, 34, 3520.
14. K. N. Raymond and C. W. Eigenbrot, Jr., Acc. Chem. Res., 1980, 13, 276.