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DOI: 10.1039/A806500D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 4081-4084

Solid state coordination chemistry of the copper cyanide–organoamine system: hydrothermal synthesis and structural characterization of [{Cu2(bpy)2(CN)}2Cu5(CN)7]·0.17H2O

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Douglas J. Chesnut, Anakarin Kusnetzow and Jon Zubieta

Abstract

The hydrothermal reaction of CuCN, KCN, 2,2′-bipyridyl (bpy) and water yields [{Cu2(bpy)2(CN)}2Cu5(CN)7]· 0.17H2O 1, a two-dimensional copper–cyano network intercalated by [(bpy)2(Cu)2(CN)]+ cations and water of crystallization.

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