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DOI: 10.1039/A806267F (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 2953-2954

1,3-Bis(silyl)cyclodisilazane: synthesis and crystal structure

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Bettina Jaschke, Regine Herbst-Irmer, Uwe Klingebiel, Peter Neugebauer and Thomas Pape

Abstract

The reaction between (Me3C)2MeSiNHLi and SiCl4 afforded R–NH–SiCl3 1, and (R–NH)2SiCl2 2; 1 reacted with BuLi with formation of the tetrachlorocyclodisilazane (RN–SiCl2)2 3, R = SiMe(CMe3)2, hydrogenation of which with LiAlH4 resulted in the first cyclodisilazane (RN–SiH2)2 4.

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