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DOI: 10.1039/A805102J (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 3771-3776

Palladium diphenyl-2-pyridylphosphine complexes

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Athanasia Dervisi, Peter G. Edwards, Paul D. Newman, Robert P. Tooze, Simon J. Coles and Michael B. Hursthouse

Abstract

The stoichiometric reaction of diphenyl-2-pyridylphosphine (Ph2PC5H4N-2) and palladium(II) acetate afforded the palladium(I) dimer [Pd2(µ-Ph2PC5H4N)2(OAc)2] 1. Attempts to isolate the monomer, [Pd(µ-Ph2PC5H4N)2(OAc)2], from 2∶1 stoichiometry reactions (Ph2PC5H4N∶Pd), resulted only in the isolation of 1. When >3 mole equivalents of Ph2PC5H4N were used the zerovalent palladium complex [Pd(Ph2PC5H4N)3] was isolated. Other palladium(I) dimers with carboxylic or sulfonic anionic ligands have been prepared by a metathesis reaction of the co-ordinated acetates. The complexes 1 and [Pd2(µ-Ph2PC5H4N)2(O2CCF3)2] 2 have been structurally characterised as head-to-tail dimers. The mononuclear complex [Pd(Ph2PC5H4N)2(O2CCF3)2] has been obtained by reaction of Ph2C5H4N with [Pd(CH3CN)2(O2CCF3)2]. Complex 1 reacts with dimethyl acetylenedicarboxylate to give [Pd2(µ-Ph2PC5H4N)2(OAc)2(µ-MeO2CC[double bond, length half m-dash]CCO2Me)], while attempts to isolate an A-frame carbonyl complex were unsuccessful.

References

  1. E. Drent, D. Arnoldy and P. H. M. Budzelaar, J. Organomet. Chem., 1993, 455, 247 CrossRef CAS.
  2. E. Drent, W. W. Jager, J. J. Keijsper and F. G. M. Niele, in Applied homogeneous catalysis with organometallic compounds, eds. B. Cornils and W. A. Hermann, VCH, Weinheim, 1996, vol. 2, p. 1119 Search PubMed.
  3. A. Scrivanti, V. Beghetto, E. Campagna, M. Zanato and U. Matteoli, Organometallics, 1998, 17, 630 CrossRef CAS.
  4. E. Drent, D. Arnoldy and P. H. M. Budzelaar, J. Organomet. Chem., 1994, 475, 57 CrossRef CAS.
  5. (a) Y. Xie, C. Lee, Y. Yang, S. Rettig and B. R. James, Can. J. Chem., 1991, 70, 751; (b) J. P. Farr, M. M. Olmstead, C. H. Hunt and A. L. Balch, Inorg. Chem., 1981, 20, 1182 CrossRef CAS; (c) G. De Munno, J. Organomet. Chem., 1993, 450, 263 CrossRef; (d) J. P. Farr, M. M. Olmstead and A. L. Balch, Inorg. Chem., 1983, 22, 1229 CrossRef CAS; (e) M. L. Kullberg and C. P. Kubiak, Organometallics, 1984, 3, 632 CrossRef CAS; (f) J. P. Farr, M. M. Olmstead, N. M. Rutherford, F. E. Wood and A. L. Balch, Organometallics, 1983, 2, 1758 CrossRef CAS; (g) C. G. Arena, F. Faraone, M. Lanfranchi, E. Rotondo and A. Tiripicchio, Inorg. Chem., 1992, 31, 4797 CrossRef.
  6. (a) F. E. Wood, J. Hvoslef, H. Hope and A. L. Balch, Inorg. Chem., 1984, 23, 4309 CrossRef CAS; (b) J. P. Farr, F. E. Wood and A. L. Balch, Inorg. Chem., 1983, 22, 3387 CrossRef CAS.
  7. L. Malatesta and M. Angoletta, J. Chem. Soc., 1957, 1186 RSC.
  8. C. Amatore, E. Carre, A. Jutand and M. A. M'Barki, Organometallics, 1995, 14, 1818 CrossRef CAS.
  9. C. Amatore, E. Carre, A. Jutand and M. A. M'Barki, Organometallics, 1992, 11, 3009 CrossRef CAS.
  10. Z.-Z. Zhang, H.-K. Wang, H.-G. Wang and R.-J. Wang, J. Organomet. Chem., 1986, 314, 357 CrossRef CAS.
  11. T. Suzuki, N. Iitaka, S. Kuradi, M. Kita, K. Kashiwava, S. Ohba and J. Fujita, Bull. Chem. Soc. Jpn., 1992, 65, 1817 CAS.
  12. T. E. Kraft, C. I. Hejna and J. S. Smith, Inorg. Chem., 1990, 29, 2682 CrossRef.
  13. D. J. Wink, Acta Crystallogr., Sect. C, 1990, 46, 56 CrossRef.
  14. K. Nakamoto, Infrared and raman spectroscopy of inorganic and coordination compounds, Wiley, New York, 4th edn., 1986, p. 232 Search PubMed.
  15. S. P. Gejji, K. Hermansson and J. Lindgren, J. Phys. Chem., 1993, 97, 3712 CrossRef CAS.
  16. G. Balimann, H. Motschi and P. S. Pregosin, Inorg. Chim. Acta, 1977, 23, 191 CrossRef CAS.
  17. M. Akita, M. Terada, S. Oyama and Y. Moro-oka, Organometallics, 1990, 9, 816 CrossRef CAS; J. H. Nelson, A. W. Verstuyft, J. D. Kelly and H. B. Jonassen, Inorg. Chem., 1974, 13, 27 CrossRef CAS; H. Hoberg and H. J. Riegel, J. Organomet. Chem., 1983, 241, 245 CrossRef CAS; H. F. Klein, B. Zettel, U. Florke and H. J. Haupt, Chem. Ber., 1992, 125, 9 CAS.
  18. A. Bacchi, M. Carcelli, M. Costa, P. Pelagatti and C. Pelizzi, Gazz. Chim. Ital., 1994, 124, 429 CAS.
  19. A. Maisonnat, J. P. Farr and A. L. Balch, Inorg. Chim. Acta, 1981, 53, L217 CrossRef CAS.
  20. M. Bochmann, Organometallics 1: complexes with transition metal carbon σ-bonds, Oxford chemistry primers, 1996, p. 13 Search PubMed.
  21. M. F. Rettig and P. M. Maitlis, Inorg. Synth, 1977, 17, 134 CAS.
  22. E. Drent, J. Organomet. Chem., 1991, 417, 235 CrossRef CAS.
  23. P. A. A. Klusener, J. C. L. Sukerbuyk and P. A. Verbrugge, Eur. Pat. Appl., EP-A-499328I, 1992 Search PubMed.
  24. S. R. Drake, M. B. Hursthouse, K. M. A. Malik and S. A. S. Miller, Inorg. Chem., 1993, 32, 4653 CrossRef CAS.
  25. G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
  26. G. M. Sheldrick, SHELXL 93, University of Göttingen, 1993.
  27. N. P. C. Walker and D. Stuart, Acta Crystallogr., Sect. A, 1983, 39, 158 CrossRef; Adapted for FAST geometry by A. Karaulov, University of Wales, Cardiff, 1991.
  28. K. Davis and K. Prout, University of Oxford, 1993.