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DOI: 10.1039/A803817A (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 2777-2778

Macropolyhedral boron-containing cluster chemistry. Mixed and multiple cluster fusion in platinaborane chemistry and the structure of [(PMe2Ph)2PtB16H17PtB10H11(PMe2Ph)] as determined by synchrotron X-ray diffraction analysis

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Jonathan Bould, William Clegg, John D. Kennedy and Simon J. Teat

Abstract

Multiple cluster fusion between [(PMe2Ph)2PtB8H12] and molten B10H14 gave the 26-boron species [(PMe2Ph)2PtB16H17PtB10H11(PMe2Ph)] which exhibits quite different structural and assembly features to the 26-boron species [(PMe3)2IrB26H24Ir(CO)(PMe3)2] previously prepared from [(PMe3)2(CO)HIrB8H12] and B10H14.

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