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DOI: 10.1039/A802991A (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 2483-2488

Reactions of vanadium, molybdenum and rhenium tris(pyrazolyl)borate-stabilised oxometal complexes with B(C6F5)3: crystal structures of [Mo{OB(C6F5)3}{HB(dmpz)3}(S2CNMe2)] and [Mo{OB(C6F5)3}{HB(dmpz)3}(OCH2CH2O)] (dmpz = 3,5-dimethylpyrazolyl)

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Linda H. Doerrer, Jane R. Galsworthy, Malcolm L. H. Green and Michael A. Leech

Abstract

The tris(pyrazolyl)borate oxometal complexes [MoO{HB(dmpz)3}L2] (dmpz = 3,5-dimethylpyrazolyl, L2 = OCH2CH2O or S2CNMe2), [VO{HB(dmpz)3}(acac)] and [ReO{HB(pz)3}L2] [pz = pyrazolyl; L2 = (OEt)2, OCH2CH2O or C2O4] reacted with the strong Lewis acid B(C6F5)3 at their M[double bond, length half m-dash]O functionality to yield stable Lewis acid–metal complex adducts. The structures of the complexes [Mo{OB(C6F5)3}{HB(dmpz)3}(S2CNMe2)] and [Mo{OB(C6F5)3}{HB(dmpz)3}(OCH2CH2O)] have been determined by X-ray crystallography.

References

  1. A. K. Rappe and W. A. Goddard III, J. Am. Chem. Soc., 1982, 104, 448 CrossRef CAS.
  2. R. A. Sheldon and J. K. Kochi, Metal-catalysed Oxidations of Organic Compounds, Academic Press, New York, 1981 Search PubMed.
  3. M. H. Chisholm and I. P. Rothwell(Editors), Alkoxides and Related O-Donor Ligands in Organometallic Chemistry, Polyhedron Symposia-in-Print no. 16, 1995, 14 Search PubMed.
  4. Metal Ligand Multiple Bonds, eds. W. A. Nugent and J. M. Mayer, Wiley, New York, 1988 Search PubMed.
  5. J. Fischer, J. Kress, J. A. Osborn, L. Ricard and M. Wesolek, Polyhedron, 1987, 6, 1839 CrossRef CAS.
  6. J. Kress, M. Wesolek, J.-P. Le Ny and J. A. Osborn, J. Chem. Soc., Chem. Commun., 1982, 1039 RSC.
  7. J. R. Galsworthy, M. L. H. Green, M. Müller and K. Prout, J. Chem. Soc., Dalton Trans., 1997, 1309 RSC.
  8. J. R. Galsworthy, J. C. Green, M. L. H. Green and M. Müller, J. Chem. Soc., Dalton Trans., 1998, 15 RSC.
  9. C. G. Young, S. A. Roberts, R. B. Ortega and J. H. Enemark, J. Am. Chem. Soc., 1987, 109, 2938 CrossRef.
  10. N. E. Heimer and W. E. Cleland, jun., Acta Crystallogr., Sect. C, 1991, 47, 56 CrossRef.
  11. W. E. Cleland, jun., K. M. Barnhart, K. Yamanouchi, D. Collison, F. E. Mabbs, R. B. Ortega and J. H. Enemark, Inorg. Chem., 1987, 26, 1017 CrossRef.
  12. E. Kime-Hunt, K. Spartalian, M. DeRusha, C. M. Nunn and C. J. Carrano, Inorg. Chem., 1989, 28, 4392 CrossRef CAS.
  13. J. M. Mayer, Inorg. Chem., 1988, 27, 3899 CrossRef CAS; T. M. Trnka and G. Parkin, Polyhedron, 1997, 16, 1031 CrossRef CAS.
  14. C. S. J. Chang, T. J. Pecci, M. D. Caducci and J. H. Enemark, Inorg. Chem., 1993, 32, 4106 CrossRef CAS.
  15. P. Basu, M. A. Bruck, Z. Li, I. K. Dhawan and J. H. Enemark, Inorg. Chem., 1995, 34, 405 CrossRef CAS.
  16. C. A. Kipke, W. E. Cleland, jun., S. A. Roberts and J. H. Enemark, Acta Crystallogr., Sect. C, 1989, 45, 870 CrossRef.
  17. S. A. Roberts, C. G. Young, W. E. Cleland, jun., R. B. Ortega and J. H. Enemark, Inorg. Chem., 1988, 27, 3044 CrossRef CAS.
  18. S. Lincoln, S.-L. Soong, S. A. Koch, M. Sato and J. H. Enemark, Inorg. Chem., 1985, 24, 1355 CrossRef.
  19. S. N. Brown and J. M. Mayer, Inorg. Chem., 1992, 31, 4091 CrossRef.
  20. D. D. Dumez and J. M. Mayer, Inorg. Chem., 1995, 34, 6396 CrossRef CAS.
  21. A. N. Chernega, A. J. Graham, M. L. H. Green, J. Haggitt, J. Lloyd, C. P. Mehnert, N. Metzler and J. Souter, J. Chem. Soc., Dalton Trans., 1997, 2293 RSC.
  22. D. Gewirth, The HKL Manual, written with the co-operation of the program authors, Z. Otwinowski and W. Minor, Yale University, 1995 Search PubMed.
  23. D. J. Watkin, C. K. Prout, J. R. Carruthers and P. W. Betteridge, CRYSTALS, Issue 10, Chemical Crystallography Laboratory, University of Oxford, 1996.
  24. International Tables for Crystallography, Kluwer, Dordrecht, 1992, vol. C Search PubMed.
  25. E. Prince, Mathematical Techniques in Crystallography and Material Sciences, Springer, New York, 1982 Search PubMed.
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