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DOI: 10.1039/A802595I (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 2665-2670

Carbonyl sulfide insertion into Group 2 metal–isopropoxide bonds; synthesis and crystal structures of [Mg(OCSOPri)2(PriOH)4]· 2PriOH and [{Sr(OCSOPri)2(PriOH)2}n]

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Izoldi K. Bezougli, Alan Bashall, Mary McPartlin and D. Michael P. Mingos

Abstract

The insertion reactions of COS into the metal–alkoxide bonds of some alkaline-earth metals have been investigated. The resulting compounds have been studied spectroscopically (IR, 1H and 13C NMR), and by analytical techniques (TGA). The crystal structures of the strontium complex [{Sr(OCSOPri)2(PriOH)2}n] and the magnesium complex [Mg(OCSOPri)2(PriOH)4]·2PriOH have shown that whereas the former has a three dimensional structure the latter is monomeric.

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