Two-fold interpenetration of 3-D nets assembled via three-co-ordinate silver(I) ions and amide–amide hydrogen bonds

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Christer B. Aakeröy, Alicia M. Beatty and Brian A. Helfrich


Abstract

The combination of isonicotinamide with AgBF4 or AgClO4, respectively, led to isostructural compounds [tris(isonicotinamide)silver(I) tetrafluoroborate and tris(isonicotinamide)silver(I) perchlorate], containing two 3-D interpenetrating nets of three-co-ordinate silver(I) ions linked by N–H[hair space][hair space]· · ·[hair space][hair space]O hydrogen bonds between adjacent isonicotinamide ligands.


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